Nitrogen Fractionation in External Galaxies

In star forming regions in our own Galaxy, the 14N/15N ratio is found to vary from $\sim$ 100 in meteorites, comets and protoplanetary disks up to $\sim$ 1000 in pre-stellar and star forming cores, while in external galaxies the very few single-dish large scale measurements of this ratio lead to values of 100-450. The extent of the contribution of isotopic fractionation to these variations is, to date, unknown. In this paper we present a theoretical chemical study of nitrogen fractionation in external galaxies in order to determine the physical conditions that may lead to a spread of the 14N/15N ratio from the solar value of $\sim$440 and hence evaluate the contribution of chemical reactions in the ISM to nitrogen fractionation. We find that the main cause of ISM enrichment of nitrogen fractionation is high gas densities, aided by high fluxes of cosmic rays.Comment: Accepted by MNRA

A high resolution study of complex organic molecules in hot cores

We present the results of a line identification analysis using data from the IRAM Plateau de Bure Inferferometer, focusing on six massive star-forming hot cores: G31.41+0.31, G29.96-0.02, G19.61-0.23, G10.62-0.38, G24.78+0.08A1 and G24.78+0.08A2. We identify several transitions of vibrationally excited methyl formate (HCOOCH$_3$) for the first time in these objects as well as transitions of other complex molecules, including ethyl cyanide (C$_2$H$_5$CN), and isocyanic acid (HNCO). We also postulate a detection of one transition of glycolaldehyde (CH$_2$(OH)CHO) in two new hot cores. We find G29.96-0.02, G19.61-0.23, G24.78+0.08A1 and 24.78+0.08A2 to be chemically very similar. G31.41+0.31, however, is chemically different: it manifests a larger chemical inventory and has significantly larger column densities. We suggest that it may represent a different evolutionary stage to the other hot cores in the sample, or it may surround a star with a higher mass. We derive column densities for methyl formate in G31.41+0.31, using the rotation diagram method, of $\times$10$^{17}$ cm$^{-2}$ and a T$_{rot}$ of $\sim$170 K. For G29.96-0.02, G24.78+0.08A1 and G24.78+0.08A2, glycolaldehyde, methyl formate and methyl cyanide all seem to trace the same material and peak at roughly the same position towards the dust emission peak. For G31.41+0.31, however, glycolaldehyde shows a different distribution to methyl formate and methyl cyanide and seems to trace the densest, most compact inner part of hot cores.Comment: Accepted to MNRA

Agnone festante nel 30 maggio 1854 solenne celebra la inaugurazione del Monte de' Pegni a monumento di devozione e di fedeltà verso Ferdinando 2. Re del regno delle Due Sicilie ... / il conte Viti sotto-intendente d'Isernia ... questa prolusione dettava ..

Agnone festante nel 30 maggio 1854 solenne celebra la inaugurazione del Monte de' Pegni a monumento di devozione e di fedeltà verso Ferdinando 2. Re del regno delle Due Sicilie ... / il conte Viti sotto-intendente d'Isernia ... questa prolusione dettava .. Napoli : Stab. Tip. del Dante, 1854 32 p. ; 24 c

Model and Solution Methods for the Mixed-Fleet Multi-Terminal Bus Scheduling Problem

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Availability-based dynamic pricing on a round-trip carsharing service: an explorative analysis using agent-based simulation

Carsharing companies aim to customize their service to increase fleet usage and revenues with different pricing schemes and offer types. Dynamic pricing policies can be designed to adjust and balance temporally and spatially cars availability but may pose some question on customers’ fairness. In this paper, we propose an explorative analysis of how an availability-based dynamic pricing scheme impacts the demand and the supply performance. The policy is simulated in MATSim and compared to a fixed pricing policy scheme. This simulation consists of analyzing the behavior of a synthetic population of car-sharing members for Berlin and the surrounding region in which is applied an availability-based dynamic pricing in which price depends on vehicle availability in booking stations. Results show that when the dynamic pricing is applied there is a light decrease in the number of bookings and people with low value of time tend to abandon the carsharing mode in favor of other modes of transportation

willingness to pay for innovation the case of the anti hcv drugs from the italian national health service perspective

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